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Hence, the correct order of bond lengths is C?C>C?H>C=C>C?C.
Bond length can be calculated in three easy steps. First, determine the type of covalent bond between the atoms (single, double or triple). Then, using a covalent radii chart, find the atomic radii in these bonds. Finally, add them together and you have the approximate bond length.
The length of the bond is determined by the number of bonded electrons (the bond order). The higher the bond order, the stronger the pull between the two atoms and the shorter the bond length.
To calculate bond length, one must draw the Lewis structure for the molecule, find the atomic radii of the two atoms on an atomic radius chart, and add the two atomic radii together. For example, the bond length of H2 is approximately 62pm, since both atoms are hydrogen atoms and their covalent radius is 31pm.
Bond order (B.O.) is defined as one-half the difference between the number of electrons present in the bonding and the anti-bonding orbitals. Bond order (B.O) = ( Number of bonding electrons - Number of the anti-bonding electron) Bond order = (Nb- Na)