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Name: Date: Mods: HOMEWORK PROBLEMS 23. The reaction 2NO(g) + Cl2(g) 2NOCl(g) was studied at 10oC. The following results were obtained. NO o 0.10 0.10 0.20 Cl2 o 0.10 0.20 0.20Initial Rate (mol/Lmin).

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Q. In the reaction, 2NO+Cl2→2NOCl, it has been found that doubling the concentration of both the reactants increases the rate by a factor of eight but doubling the chlorine concentration alone only doubles the rate.

2NOCl(g)⇌2NO(g)+Cl2(g) the value of equilibrium constant Kc is 3. 75×10−4 at 1069K.

The reaction 2NO(g)+Cl2(g)→2NOCl(g) is second order in NO and first order in Cl2.

The equilibrium constant, K, for 2 NO (g) + O2 (g) ⇌ 2 NO2 (g) is 6.9 x 102.

2NOCI(g) = 2NO(g) + Cl2(g) AH° = 18 Kcal & Asº = 30 cal/K at 300 K. The equilibrium constant, Kp of the reaction at 300 K is e15 08-15 Oe-18 e-12.

For the equilibrium, 2 NOCl ( g ) Nitrosyl chloride ⇌ 2 NO ( g ) Nitric oxide + Cl 2 ( g ) chlorine . The value of the equilibrium constant is. 75 × 10 - 4 at .

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