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2 - 14 April 2011 NH Harrington Hall Hotel London, UK A 3 day Course presented by Professor Victor Snieckus Queen s University, Ontario, Canada Constructed and regularly updated with the invaluable assistance of current members of the VS Group We ve Got Got Chemistry Chemistry We ve www.scientificupdate.co.uk info scientificupdate.co.uk Scientific Update Training Courses 2011 Directed ortho Metalation,Transition Metal Catalyzed Coupling, and C-H Activation Contemporary Synthetic.

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tert-Butyllithium is a chemical compound with the formula (CH3)3CLi. As an organolithium compound, it has applications in organic synthesis since it is a strong base, capable of deprotonating many carbon molecules, including benzene.

Directed ortho-lithiation of an aromatic compound 1 involves removal of a proton from a site ortho to a directing metalating group (DMG) that incorporates a heteroatom, usually oxygen, nitrogen or sulfur.

N-butyllithium, abbreviated n-BuLi, is an organolithium reagent that is frequently used as a strong base or as a nucleophile. N-butyllithium is commercially available as a solution in alkanes such as hexane or heptane.

Butyllithium is a strong base (pKb ≈ -36), but it is also a powerful nucleophile and reductant, depending on the other reactants.

Directed ortho metalation (DoM) is an adaptation of electrophilic aromatic substitution in which electrophiles attach themselves exclusively to the ortho- position of a direct metalation group or DMG through the intermediary of an aryllithium compound. The DMG interacts with lithium through a hetero atom.

Expert-Verified Answer. The bases that can deprotonate a terminal alkyne are n-BuLi, LDA, and NaOMe.

The basicity of alkyllithium compounds are influenced by other molecules present. For example, whereas n-butyllithium is not basic enough to deprotonate aromatic compounds, the addition of tetramethylethylenediamine (TMEDA) increases its basicity to form lithiated arenes.

The first deprotonation of benzene was achieved with ethylsodium in 1908. Although alkyllithiums do not deprotonate benzene in n-hexane or ether solvents,4 they may accomplish the deprotonation of benzene in the presence of potassium alkoxide (superbase)5 or chelating diamine ligands.

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Form Packages
Adoption
Bankruptcy
Contractors
Divorce
Home Sales
Employment
Identity Theft
Incorporation
Landlord Tenant
Living Trust
Name Change
Personal Planning
Small Business
Wills & Estates
Packages A-Z
Form Categories
Affidavits
Bankruptcy
Bill of Sale
Corporate - LLC
Divorce
Employment
Identity Theft
Internet Technology
Landlord Tenant
Living Wills
Name Change
Power of Attorney
Real Estate
Small Estates
Wills
All Forms
Forms A-Z
Form Library
Customer Service
Terms of Service
Privacy Notice
Legal Hub
Content Takedown Policy
Bug Bounty Program
About Us
Help Portal
Legal Resources
Blog
Affiliates
Contact Us
Delete My Account
Site Map
Industries
Forms in Spanish
Localized Forms
State-specific Forms
Forms Kit
Legal Guides
Real Estate Handbook
All Guides
Prepared for You
Notarize
Incorporation services
Our Customers
For Consumers
For Small Business
For Attorneys
Our Sites
US Legal Forms
USLegal
FormsPass
pdfFiller
signNow
airSlate WorkFlow
DocHub
Instapage
Social Media
Call us now toll free:
+1 833 426 79 33
As seen in:
  • USA Today logo picture
  • CBC News logo picture
  • LA Times logo picture
  • The Washington Post logo picture
  • AP logo picture
  • Forbes logo picture
© Copyright 1997-2025
airSlate Legal Forms, Inc.
3720 Flowood Dr, Flowood, Mississippi 39232