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24 36 Theory of adsorption 38 2.6.1 Adsorption 38 2.6.2 Types of adsorption 38 2.6.3 Adsorbent 40 2.6.4 Physical properties of adsorbent 41 2.6.5 Selectivity of adsorbent 41 2.7 Adsorption equilibria 42 2.8 Types of adsorption isotherms 45 2.8.1 Typical isotherm 45 2.8.2 Henry s law 46 2.8.3 Langmuir isotherm 47 2.8.4 Freundlich isotherm 48 Adsorption kinetic 49 2.9.1 Pseudo-first order equation 49 2.9.2 Pseudo-second order equation 50 2.9.3 Intraparticle dif.

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Langmuir's adsorption equation which describes the amount of gas adsorbed on a solid surface is written as `(P)/(x//m)=(1)/(ab)+(P)/(b)` where `x//m` is the extent of adsorption, `a` and `b` are constants and `P` is the gas pressure.

The integral equation proposed by Ward and Tordai77 represents a general relationship between the dynamic adsorption Γ(t) and the subsurface concentration c(0, t), and reads for fresh and non-deformed surfaces: 1.20 Γ ( t ) = 2 D π [ c 0 t − ∫ 0 t c ( 0 , t − t ′ ) d ( t ′ ) ] .

The adsorption equation of the isotherm is represented as: x/m = Kp1/n where x is the adsorbate mass, m is the adsorbent mass, n and K are constants for an adsorbent and adsorbate at a temperature and 1/n is essentially the value at high pressure which is 0 with p being pressure.

Type V isotherm is similar variation of Type III obtained when water vapour is adsorbed on activated carbon at 100 oC. Adsorption isotherms are most commonly used to select the adsorbent or even the adsorption process as a unit operation for the adsorptive separation of gases.

Type I: microporous; Type II: non-porous or macroporous; Type III: non-porous or macroporous with weak interaction; Type IV: mesoporous; Type V: mesoporous with weak interaction; Type VI: layer-by-layer adsorption.

Here in this article, we will understand the adsorption meaning, types of adsorption like chemical adsorption, physical adsorption, isothermal adsorption. Also, we will discuss different adsorbate and adsorbent.

Type IV Isotherm Type IV isotherms (Figure 2.3. 9 ) occur when capillary condensation occurs. Gases condense in the tiny capillary pores of the solid at pressures below the saturation pressure of the gas. At the lower pressure regions, it shows the formation of a monolayer followed by a formation of multilayers.

Freundlich isotherm explains the behaviour of adsorption accurately. In the equation – x/m = k.P1/n (n > 1), 'k' and 'n' are constants that depend on the nature of the adsorbent and the gas at a particular temperature.

Freundlich adsorption isotherm c = equilibrium concentration of adsorbate in case of experiments made with an aqueous solution in contact with a dispersed solid phase (dissolved species/adsorbed species).

Vapor adsorption on porous materials for non-wetting adsorbent–adsorbate pairs, characterized by a Type 5 isotherm, results in low loading at low relative pressure and increased loading due to capillary condensation behavior at higher relative pressure.

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© Copyright 1997-2026
airSlate Legal Forms, Inc.
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Form Packages
Adoption
Bankruptcy
Contractors
Divorce
Home Sales
Employment
Identity Theft
Incorporation
Landlord Tenant
Living Trust
Name Change
Personal Planning
Small Business
Wills & Estates
Packages A-Z
Form Categories
Affidavits
Bankruptcy
Bill of Sale
Corporate - LLC
Divorce
Employment
Identity Theft
Internet Technology
Landlord Tenant
Living Wills
Name Change
Power of Attorney
Real Estate
Small Estates
Wills
All Forms
Forms A-Z
Form Library
Customer Service
Your Privacy Choices
Terms of Service
Privacy Notice
Legal Hub
Content Takedown Policy
Bug Bounty Program
About Us
Help Portal
Legal Resources
Blog
Affiliates
Contact Us
Delete My Account
Site Map
Industries
Forms in Spanish
Localized Forms
State-specific Forms
Forms Kit
Legal Guides
Real Estate Handbook
All Guides
Prepared for You
Notarize
Incorporation services
Our Customers
For Consumers
For Small Business
For Attorneys
Our Sites
US Legal Forms
USLegal
FormsPass
pdfFiller
signNow
altaFlow
DocHub
Instapage
Social Media
Call us now toll free:
+1 833 426 79 33
As seen in:
  • USA Today logo picture
  • CBC News logo picture
  • LA Times logo picture
  • The Washington Post logo picture
  • AP logo picture
  • Forbes logo picture
© Copyright 1997-2026
airSlate Legal Forms, Inc.
3720 Flowood Dr, Flowood, Mississippi 39232