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Dealing with Matrix Interferences in the Determination of the Priority Pollutant Metals by Furnace AA Application Note Atomic Absorption Authors Lucinda M. Voth lntroduction Atomic absorption methods.

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The matrix effect is the effect on an analytical assay caused by all other sample components except the specific compound (analyte) to be analyzed.

This problem is readily overcome by adding an excess (ca. 100- fold) of a more easily ionized element such as K, Cs, or Sr to suppress ionization in both sample and calibration solutions. The more easily ionized atoms produce a large concentration of electrons in the vapor.

Laboratory Analysis Interference, also referred to as matrix interference, occurs when non-target analytes or physical/chemical characteristics of a sample prevent quantification of the analytes of interest. This can cause increased uncertainty in the result reported to the client.

Flame noise, spectral interferences and chemical interferences are all examples of matrix effects. Atomic methods are among the most sensitive of all analysis methods to matrix effects.

Finally, many interferences due to the sample's matrix are eliminated by increasing the atomization temperature. For example, switching to a higher temperature flame helps prevents the formation of interfering oxides and hydroxides.

Typically, matrix effects are caused by co-eluting matrix components that alter the ionization of target analytes as well as the chromatographic response of target analytes, leading to reduced or increased sensitivity of the analysis.

Matrix effects are often caused by the alteration of ionization efficiency of target analytes in the presence of co-eluting compounds in the same matrix. Matrix effects can be observed either as a loss in response (ion suppression) or as an increase in response (ion enhancement).

Matrix interferences. Matrix interference is a physical interference, and can either suppress or enhance absorbance signal of analyte. It occurs when components of sample matrix other than the analyte react to form molecular species and sample background.

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Form Packages
Adoption
Bankruptcy
Contractors
Divorce
Home Sales
Employment
Identity Theft
Incorporation
Landlord Tenant
Living Trust
Name Change
Personal Planning
Small Business
Wills & Estates
Packages A-Z
Form Categories
Affidavits
Bankruptcy
Bill of Sale
Corporate - LLC
Divorce
Employment
Identity Theft
Internet Technology
Landlord Tenant
Living Wills
Name Change
Power of Attorney
Real Estate
Small Estates
Wills
All Forms
Forms A-Z
Form Library
Customer Service
Terms of Service
DMCA Policy
About Us
Blog
Affiliates
Contact Us
Privacy Notice
Delete My Account
Site Map
All Forms
Search all Forms
Industries
Forms in Spanish
Localized Forms
Legal Guides
Real Estate Handbook
All Guides
Prepared for You
Notarize
Incorporation services
Our Customers
For Consumers
For Small Business
For Attorneys
Our Sites
US Legal Forms
USLegal
FormsPass
pdfFiller
signNow
airSlate workflows
DocHub
Instapage
Social Media
Call us now toll free:
1-877-389-0141
As seen in:
  • USA Today logo picture
  • CBC News logo picture
  • LA Times logo picture
  • The Washington Post logo picture
  • AP logo picture
  • Forbes logo picture
© Copyright 1997-2025
airSlate Legal Forms, Inc.
3720 Flowood Dr, Flowood, Mississippi 39232