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U,a,b Zi-Zhou Wang,a Li-Zi Yang,a Cun-Yuan Zhaoa and Tong-Bu Lu*a Received 12th October 2009, Accepted 10th March 2010 First published as an Advance Article on the web 24th March 2010 DOI: 10.1039/b921141a The enantiopure agents d- and l-leucine, selectively bind RR and SS enantiomers from a racemate Ni(a-rac-L) 2+ to give Ni(RR-L)(d-HLeu) (ClO4 )2 n (D-1) and Ni(SS-L)(l-HLeu) (ClO4 )2 n (K-1), respectively, and leave the corresponding uninteracted SS and RR enantiomers of Ni(a-SS-L) (Cl.

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